A novel route to organonitrites by Pd-catalyzed cross-coupling of sodium nitrite and potassium organotrifluoroborates.

نویسندگان

  • Mohammad Al-Masum
  • Nabil Saleh
  • Tasfia Islam
چکیده

Microwave irradiated palladium-catalyzed cross-coupling reaction of potassium styryltrifluoroborates and sodium nitrite gives the corresponding styryl nitrites in high yields. Potassium aryltrifluoroborates also furnish aryl nitrites under same reaction condition. This unprecedented cross-coupling is an interesting development and has the potential to lead to new nitration protocols.

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عنوان ژورنال:
  • Tetrahedron letters

دوره 54 9  شماره 

صفحات  -

تاریخ انتشار 2013